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EFFECT OF THE LIGHT QUANTUM EFFICIENCY ON THE SYNCHRONOUS PHOTO CATALYTIC ABATEMENT OF SO2–NOX BINARY GAS

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Volume 7, Issue 3, Pp 67-73, 2025

DOI: https://doi.org/10.61784/ejst3091

Author(s)

Kuo Yao1#, JingLi Gao1,2#, Yasser M. A. Mohamed3*, YingHui Han1*

Affiliation(s)

1College of Resources and Environment, University of Chinese Academy of Sciences, Beijing 101408, China.

2School of Mathematics & Physics, North China Electric Power University, Baoding 071003, China.

3Photochemistry Department, National Research Centre, Dokki, Giza, P. O. 12622, Egypt.

Corresponding Author

Yasser M. A. Mohamed, YingHui Han

ABSTRACT

Photocatalytic decontamination has emerged as a highly promising technology for air pollutant control and energy conversion. In this work, a semiconductor photocatalyst was synthesized via a hydrothermal method, featuring nano-sized TiO2 doped with nickel (Ni), zirconium (Zr), and nonmetallic nitrogen (N). The kinetic process of synchronous abatement of the SO2-NOx binary gas system was systematically investigated in a self-designed photocatalytic reactor. From the perspective of quantum optics, a light quantum efficiency model was established to elaborate the photocatalytic degradation mechanism, accompanied by a detailed analysis of the synergistic effects of multiple influencing factors on the interaction between incident light and pollutants. Experimental results revealed that flue gas concentrations exert significant impacts on contaminant removal efficiencies. Notably, the experimental data showed excellent consistency with the calculated results across a wide range of operational conditions.

KEYWORDS

Photocatalysis; Simultaneous desulfurization and denitrification; Quantum efficiency; Reaction mechanism

CITE THIS PAPER

Kuo Yao, JingLi Gao, Yasser M. A. Mohamed, YingHui Han. Effect of the light quantum efficiency on the synchronous photo catalytic abatement of SO2–NOx binary gas. Eurasia Journal of Science and Technology. 2025, 7(3): 67-73. DOI: https://doi.org/10.61784/ejst3091.

REFERENCES

[1] WU Y, ZOU L, ZHU H. Improved combustion of NH3/C2H4 with Ni modified Fe-based catalyst. Chemical Engineering Journal, 2023, 472: 145187.

[2] YANG L, WANG S, CHEN C. Monitoring and Leak Diagnostics of Sulfur Hexafluoride and Decomposition Gases from Power Equipment for the Reliability and Safety of Power Grid Operation. Applied Sciences, 2024, 14(9): 3844.

[3] RAJAGOPALAN S, BROOK R D, SALERNO P R V O. Air pollution exposure and cardiometabolic risk. The Lancet Diabetes & Endocrinology, 2024, 12(3): 196-208.

[4] BOYJOO Y, SUN H, LIU J. A review on photocatalysis for air treatment: From catalyst development to reactor design. Chemical Engineering Journal, 2017, 310: 537-559.

[5] WANG X, DUAN R, LI Z. The Critical Role of Oxygen Vacancies in N2O Decomposition Over Cobalt-Doped CeO2 Catalysts. Environmental Science & Technology, 2025, 59(11): 5839-5847.

[6] MARTIN S T, LEE A T, HOFFMANN M R. Chemical mechanism of inorganic oxidants in the TiO2/UV process: increased rates of degradation of chlorinated hydrocarbons. Environmental Science & Technology, 1995, 29(10): 2567-2573.

[7] ALAHIANE S, SENNAOUI A, SAKR F. Synchronous role of coupled adsorption-photocatalytic degradation of Direct Red 80 with nanocrystalline TiO2-coated non-woven fibres materials in a static batch photoreactor. Groundwater for Sustainable Development, 2020, 11: 100396.

[8] YUAN Y, ZHANG J, LI H. Simultaneous removal of SO2, NO and mercury using TiO2-aluminum silicate fiber by photocatalysis. Chemical Engineering Journal, 2012, 192: 21-28.

[9] CHEN M, CHU J W. NOx photocatalytic degradation on active concrete road surface — from experiment to real-scale application. Journal of Cleaner Production, 2011, 19(11): 1266-1272.

[10] WANG S, WANG S, WANG J. Achieving 20% Efficiency in Organic Solar Cells Through Conformationally Locked Solid Additives. Advanced Energy Materials, 2025: 2405205.

[11] M S A, HYAM R S. Au nanoparticles decorated titanium dioxide nanotube arrays with enhanced photocatalytic dye degradation under ultraviolet and sunlight irradiation. Results in Surfaces and Interfaces, 2023, 12: 100140.

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